
A story on NPR last week about the debatable benefits of flouride in water got me asking questions about water flouridation. What form of flouride do they use? Through what mechanism is flouride in water supposed to help prevent tooth decay? What evidence is there that flouride might be harmful?
The first thing to notice is that it is flouride that is put in water, not flourine. Flourine is the elemental form -- this is what is listed on the periodic table. Flourine is a halogen; it is highly reactive and is rarely found on its own in nature. But, like all halogens, it can form a bond with itself and make a flourine molecule. Flourine (F2) is a highly toxic pale yellow gas. No wonder people are worried about putting it in water. But remember -- it is not flourine that we put in drinking water, it is floride. The difference between -ine and -ide is a big one, it is the difference of a single electron, but that single electron change the entire chemistry of the substance.
Flouride is a flourine ion, a flourine that has gained one electron and now has a positive charge. Where did it get that extra electron? Probably by making an ionic bond. Think of table salt: sodium chloride or NaCl. Chlorine is also a toxic gas, but when it makes an ionic bond with sodium, it forms the compound NaCl, which is not only not toxic, but necessary for a healthy body.
So back to flouride.
Whether or not to put flouride in driking water is a debate that has been raging for years. According to a story from Chemistry and Engineering News from 1988, it looks like many claims are still at issue. Here is what the government has to say about things right now. Have ideas changes since 1988? Do we have new evidence to support either side? What is your opinion?

